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New research describes the evolution of nanostructural lithium atoms (blue) depositing onto an electrode (yellow) during the battery charging operation.

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Idaho National Laboratory Researchers Quest To Improve Battery Performance; Glassy Li metal anode for high-performance rechargeable Li batteries

New research describes the evolution of nanostructural lithium atoms (blue) depositing onto an electrode (yellow) during the battery charging operation. Image Courtesy of Idaho National Laboratory

Researchers from Idaho National Laboratory working with the University of California, San Diego have shown improvements in charging behavior. The findings suggest strategies that will enhance recharging, and increase battery longevity. The compelling research for making glassy metals:

Compared to crystalline lithium, glassy lithium outperforms in electrochemical reversibility and is a desired structure for high-energy rechargeable batteries, the authors wrote.”

The study published in Nature Materials by Wang, X., Pawar, G., Li, Y. et al. Glassy Li metal anode for high-performance rechargeable Li batteries. Nat. Mater. (2020). https://doi.org/10.1038/s41563-020-0729-1

Here, cryogenic transmission electron microscopy was used to reveal the evolving nanostructure of Li metal deposits at various transient states in the nucleation and growth process, in which a disorder–order phase transition was observed as a function of current density and deposition time. The atomic interaction over wide spatial and temporal scales was depicted by reactive molecular dynamics simulations to assist in understanding the kinetics. Compared to crystalline Li, glassy Li outperforms in electrochemical reversibility, and it has a desired structure for high-energy rechargeable Li batteries.

 

Our findings correlate the crystallinity of the nuclei with the subsequent growth of the nanostructure and morphology, and provide strategies to control and shape the mesostructure of Li metal to achieve high performance in rechargeable Li batteries.

—Wang et al.

Full story:

QUEST TO IMPROVE BATTERY PERFORMANCE LEADS TO DISCOVERY OF RARE GLASSY METAL

Originally published by Idaho National Laboratory

Materials scientists scrutinizing the first few moments of battery recharging encountered an astonishing entity. Their discovery defied expectations, logic and experience. More importantly, it may open the door to better batteries, faster catalysts and other materials science leaps.

Scientists from Idaho National Laboratory and University of California San Diego investigated the earliest stages of lithium recharging at the atomic level. To their surprise, they learned that slow, low-energy charging caused lithium atoms to deposit on electrodes in a disorganized way that improves charging behavior. This noncrystalline “glassy” lithium had never been observed, and creating such amorphous metals has traditionally been extremely difficult.

The findings suggest strategies for fine-tuning recharging approaches to boost battery life and—intriguingly—for making glassy metals for other applications. The study appeared online this week in Nature Materials.

CHARGING KNOWNS, UNKNOWNS

Lithium metal is considered an ideal anode for high-energy rechargeable batteries, which must be lightweight yet store a lot of energy. Recharging such batteries involves depositing lithium atoms onto the anode surface, a process that is not well understood at the atomic level.

Scientists know that lithium metal anodes can recharge erratically and, as a result, cannot withstand many recharging cycles. The way lithium atoms deposit onto the anode can vary from one recharge cycle to the next, likely influenced by the earliest congregation of the first few atoms, a process known as nucleation.

“That initial nucleation may affect your battery performance, safety and reliability,” said Gorakh Pawar, an INL staff scientist and one of the paper’s two lead authors. “It is critical to comprehend the underlying mechanism of lithium deposition…especially in the very early stage of nucleation,” they wrote.

WATCHING LITHIUM EMBRYOS FORM

To discover how lithium atoms first come together during recharging, the researchers combined images and analyses from a powerful electron microscope with liquid-nitrogen cooling and computer modeling. The pioneering cryo-state electron microscopy approach allowed them to see the creation of lithium metal “embryos,” and the computer simulations helped explain what they saw.

Lithium, like other metals, typically exists in a structured crystalline phase. Such “grainy” lithium can lead to inconsistent recharging and shorts because crystals can grow in various shapes, Pawar said. Inconsistent lithium growth progression from one recharge cycle to another results in irregular shapes (aka dendrites) and can shorten battery life.

When the research team sought to understand the initial nucleation process, they were surprised to learn that certain conditions created a less structured form of lithium that was amorphous (like glass) rather than crystalline (like diamond).

“The power of cryogenic imaging to discover new phenomena in materials science is showcased in this work,” said Shirley Meng, who led UC San Diego’s pioneering cryo-microscopy work. She said the imaging and spectroscopic data obtained are often convoluted and complicated, noting, “It is true teamwork that enabled us to interpret the experimental data with confidence because the computational modeling helped decipher the complexity.”

A GLASSY SURPRISE

Compared to crystalline lithium, glassy lithium outperforms in electrochemical reversibility and is a desired structure for high-energy rechargeable batteries,” the authors wrote. The finding came as a shock because pure amorphous elemental metals had never been observed before. They are extremely difficult to produce, and only a few metal mixtures (alloys) have been observed with a “glassy” configuration, which imparts powerful material properties.

What’s more, the team learned that a glassy lithium embryo is more likely to retain its amorphous structure throughout growth. As the researchers worked to understand what conditions favored glassy nucleation, they were shocked again.

“We can make amorphous metal in very mild conditions at a very slow charging rate,” said Boryann Liaw, an INL directorate fellow and INL lead on the work. “It’s quite surprising.”

That outcome was counterintuitive because it was thought that slow deposition rates would allow the atoms to find their way into an ordered array — grainy lithium. To find glassy lithium under such conditions was considered unthinkable, Liaw said. Modeling work explained how reaction kinetics compete with crystallization to drive the glassy formation. The team confirmed those findings by creating glassy forms of four more reactive metals that are attractive for battery applications.

WHAT’S NEXT?

The research suggests how to better achieve glassy lithium deposits during recharging of high-energy batteries. When applied, the result could help meet the goals of the Battery500 consortium, a Department of Energy initiative that funded the research. The consortium aims to develop commercially viable electric vehicle batteries with a cell level specific energy of 500 Wh/kg.

“The real innovation has to come from very basic scientific understanding of any materials or processes,” Liaw said. Plus, this new understanding could lead to more effective metal catalysts, stronger metal coatings and other applications that could benefit from glassy metals.

.Correlation between crystallinity of Li metal and performance (left) and strategies to achieve better performance (right). The performance (left) is specified as the electrochemical performance of Li metal as an anode for Li metal batteries, including high Coulombic efficiency (CE), long cycling life, low volume change and absence of Li dendrites. The structural connection is referred to as the capability to maintain the electronic and ionic pathway for charge transfer and ion transportation; poor structural connection will facilitate lost electrochemical activity and form ‘dead’ Li. The electrochemical reversibility is measured by the content ratio of the stripped Li by plated Li, which should be close to 100%. The ideal deposit density should be consistent with the theoretical density of Li metal (0.534 g cm–3). The proposed strategies such as using the 3D substrate, changing current density, engineering interphase and designing electrolytes can alter the energy transfer and mass transfer of EDLi during nucleation and growth, thus resulting in varied crystallinity of EDLi. Wang et al.

 
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